Abstract

Here, we report the synthesis of copper–manganese alloy (CuMnO2) using graphitic carbon nitride (gCN) as a novel support material. The successful formation of CuMnO2-gCN was confirmed through spectroscopic, optical, and other characterization techniques. We have applied this catalyst as the energy storage material in the alkaline media and it has shown good catalytic behavior in supercapacitor applications. The CuMnO2-gCN demonstrates outstanding electrocapacitive performance, having high capacitance (817.85 A·g−1) and well-cycling stability (1000 cycles) when used as a working electrode material for supercapacitor applications. For comparison, we have also used the gCN and Cu2O-gCN for supercapacitor applications. This study proposes a simple path for the extensive construction of self-attaining double metal alloy with control size and uniformity in high-performance energy-storing materials.

Highlights

  • There is a great thrust on the usage of two-dimensional (2D) graphitic carbon nanomaterials for energy storage owing to their novel electronic and other characteristics [1,2,3].The faradic response within 2D graphitic carbon advances their electrochemical energy storing activity and, for this, the overview of heteroatoms, for example, nitrogen, must be confirmed as a capable method [4,5,6,7]

  • The pale-yellow-stock material graphitic carbon nitride (gCN) was rinsed numerous times using deionized water to eliminate the remaining alkaline sorts over the specimen exterior and again dried at 60 ◦ C

  • While we introduced the Mn to the above system, the nature of the material changed from the crystalline to amorphous and the peaks corresponding to the Cu2 O gone in the final CuMnO2 -gCN product

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Summary

Introduction

There is a great thrust on the usage of two-dimensional (2D) graphitic carbon nanomaterials for energy storage owing to their novel electronic and other characteristics [1,2,3].The faradic response within 2D graphitic carbon advances their electrochemical energy storing activity and, for this, the overview of heteroatoms, for example, nitrogen, must be confirmed as a capable method [4,5,6,7]. There is a great thrust on the usage of two-dimensional (2D) graphitic carbon nanomaterials for energy storage owing to their novel electronic and other characteristics [1,2,3]. The growth of environmentally-friendly energy renovation/storing strategies has developed significant worries that require sufficient explanation to preserve the feasibility of our atmosphere. In this direction, supercapacitor denotes a novel type of energy storing strategy among economical capacitors, as well as for chargeable batteries, which carries high power density along with an extensive lifecycle [12,13]. Its small energy density (

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