Graphite nanoparticles-dispersed paraffin/water emulsion with enhanced thermal-physical property and photo-thermal performance

Abstract

In this paper, graphite nanoparticles have been dispersed into a paraffin/water emulsion with the purpose of improving the thermal conductivity and photothermal conversion performance of the emulsion. The melting enthalpy and apparent specific heat of 20wt% paraffin/water emulsion is 39.2Jg−1 and 9.105Jg−1K−1 and its melting and freezing temperatures are very close to those of paraffin. Moreover, the 300 heating–cooling cycles test indicates that the paraffin/water emulsions containing 0.1wt% graphite exhibits good thermal reliability. The viscosities of all samples are lower than 0.0750Pas, meeting the transportablilty requirements in pump systems for applications. In addition, the thermal conductivity of the emulsion containing 0.1wt% graphite increases by 20.0% as compared to the base fluid and its receiver efficiency is higher than 86.0% as the temperature ranges from room temperature to 80°C. As a result, the paraffin/water emulsion containing graphite with high energy storage capacity, enhanced thermal conductivity and excellent photo-thermal performance, good thermal reliability and good fluidity shows great potential for use as advanced heat transfer fluid (HTF) in the low temperature applications of direct absorption solar collector (DASCs).