Abstract

Abstract The Raman spectra comparative study of graphite-like modifications of carbon: monocrystalline graphite, pyrolytic graphite and amorphous (glassy) carbon was performed at high pressures and room temperature. At P = 44 GPa an abrupt broadening of Raman bands of pyrolytic graphite and glassy carbon was observed. The same process in monocrystalline graphite occures continuously from 23 to 44 GPa and for higher pressures the Raman spectra of all three substances under study become practically indistinguishable from one another and from that of amorphous carbon (a-C) at the same pressure. This result is ascribed to the formation at these pressures of the dence amorphous carbon modification.

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