Abstract
AbstractThe cover picture shows a cyclohexallene‐based starry night over the cathedral of Santiago de Compostela in northwest Spain. 1,2‐Cyclohexadiene is a highly reactive cyclic allene that is usually generated by the use of strong bases or highly nucleophilic reagents, and this limits its scope. Herein we described an improved method to generate this molecule by fluoride‐induced β‐elimination of the corresponding 6‐(trimethylsilyl)cyclohexenyl triflate. This method allows the generation of this strained cyclic allene under mild reaction conditions and with higher efficiency than classical approaches, as demonstrated by trapping experiments based on cycloaddition reactions. Details are discussed in the article by D. Peña et al. on p. 5519 ff.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
