Graphene-Based Hierarchically Micro/Mesoporous Nanocomposites as Sulfur Immobilizers for High-Performance Lithium–Sulfur Batteries

Abstract

Herein, a hierarchically micro/mesoporous nanocomposite of graphene and carbon nanospheres (HGC) is used as an immobilizer for a lithium–sulfur (Li–S) battery with enhanced performance. HGC derived from graphene oxides and polyvinylidene fluoride polymers, combined with the advantages of graphene and porous carbon nanospheres, exhibits a hierarchically micro/mesoporous structure with an ultralarge specific surface area of up to 3182 m2 g–1 and a large pore volume of 1.91 cm3 g–1. Graphene as a conducting network can enhance electronic conductivity, while porous nanospheres like a reservoir can effectively store and immobilize sulfur particles. HGC/sulfur electrode material obtained via a melting infusion process exhibits high reversible specific capacity of 1250 mA h g–1 with a high sulfur content of 74.5 wt %, and it still has a capacity of 916 mA h g–1 after 100 cycles, which is better than that of pristine porous graphene and carbon nanospheres. Furthermore, the relative capacity decay of the HGC/sulfu...