Abstract

Owing to the remarkable chemical and physical properties, graphene has been widely investigated by researchers over the last 15 years. This review summarizes major synthetic methods such as mechanical exfoliation, liquid phase exfoliation, unzipping of carbon nanotube, oxidation-reduction, arc discharge, chemical vapor deposition, and epitaxial growth of graphene in silicon carbide. Recent advances in the application of graphene in graphene-based lithium ion batteries, supercapacitors, electrochemical sensors, transparent electrodes and environmental based remedies are discussed.

Highlights

  • Graphene has been extensively studied by scientific and engineering communities for more than 15 years since its first fabrication reported in 2004 [1]

  • N-doped graphene nanosheets and nanoparticles incorporated graphene have been investigated to improve the performance of the lithium ion batteries

  • The incorporation of nitrogen with graphene increases specific area and electron transfer within the network of graphene. Metal oxide nanoparticles such as RuO2, NiO2, MnO2, Co3 O4, ZnO and SnO2 and carbon nanotubes (CNT)-graphene have been incorporated with graphene to boost the performance of the super capacitors

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Summary

Introduction

Graphene has been extensively studied by scientific and engineering communities for more than 15 years since its first fabrication reported in 2004 [1]. Graphene oxide comprises various functional groups containing oxygen (see Figure 2) These functional groups are mostly hydroxyl and epoxide groups in the basal planes and consist of trace amount of carbonyl, carboxyl, phenol, lactone and quinone groups at the edges of the sheet [32]. The wide range of these functional groups at the edges and the basal planes of graphene oxide make it functionalized and exfoliated to yield well dispersed solutions of separate graphene oxide sheets in polar and non-polar solutions and it has a wide range of applications in nanocomposites [33], photocatalysis [34], battery [35], capacitors [36] and sensors [37].

Synthesis
Mechanical
Liquid
Unzipping of Carbon
OH and hydrazine
Arc Discharge Method
Chemical Vapor Deposition of Graphene on Nickel
Chemical Vapor Synthesis of Graphene on Copper
Oxidation-Reduction
Lithium Ion Batteries
Supercapacitors
Electrochemical Sensors
Transparent Electrodes
Environmental Applications
Adsorption of Metal Ions
Adsorption of Gases
Graphene Based Photocatalyst
Findings
Conclusions
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