Graphene oxide wrapped melamine sponge as an efficient and recoverable adsorbent for Pb(II) removal from fly ash leachate.

Abstract

Lead is one of the most toxic elements, which has been well recognized for its negative effect on the environment and human beings. But, preliminary methods such as chemical precipitation, membrane separation etc. and commonly used adsorbents based on adsorption technology were found to be expensive and inefficient. In this study, we modify the surface of melamine sponge (MS) with polydopamine (PDA) and then coat with glutathione/graphene oxide (GG) as the adsorbent (MS@GG) to removal Pb(II) from aqueous solutions and fly ash leachate. The maximum adsorption capacity of MS@GG was calculated to be 349.7 mg Pb/g GG, and the reaction reached equilibrium in 30 min which were both higher than raw GG material and most previously reported adsorbents due to active sites on the surface of GG, as well as the unique macroporous and hydrophilic structure of MS. Meanwhile, based on its easy separation, by using HCl as the regeneration agent, the materials revealed good reproducibility. In addition, when MS@GG was applied for the removal of Pb(II) in fly ash leachate, the removal efficiency reached up to 99.24%, indicating that the novel MS@GG was the promising candidate adsorbent material for Pb(II) removal.