Graphene oxide@Fe3O4-decorated iota-carrageenan composite for ultra-fast and highly efficient adsorption of lead (II) from water

Abstract

The aggravated problem of lead pollution, especially in aquatic environments, necessitates the development of eminent adsorbents that could radically solve this environmental problem. Hence, a new composite was constructed based on iota carrageenan (i.Carr), graphene oxide (GO) and magnetite (Fe3O4) for removing noxious Pb2+ ions. The GO@Fe3O4-i.Carr composite was characterized by VSM, SEM, XPS, XRD, FTIR and Zeta potential. The removal of Pb2+ ions attained a quick equilibrium of almost 30 min with a removal efficiency reaching 93.68 %. The removal of Pb2+ was boosted significantly, in the order of GO@Fe3O4-i.Carr(1:1) > GO@Fe3O4-i.Carr(1:3) > GO@Fe3O4-i.Carr(3:1). Moreover, acquired experimental data fitted the pseudo 2nd order kinetic model and Freundlich isotherm model with a maximal monolayer adsorption capacity reached 440.05 mg/g. Notably, after five adsorption runs, the composite maintained its removal efficiency exceeding 74 %. The assumed adsorption mechanisms of Pb2+ onto GO@Fe3O4-i.Carr were complexation, precipitation, Lewis acid-base, and electrostatic attraction forces. Overall, the GO@Fe3O4-i.Carr composite elucidated the auspicious adsorbent criteria, comprising fast adsorption with high performance, ease-separation and tolerable recyclability, advising its feasible use to decontaminate water bodies from hazardous heavy metals.