Graphene oxide and graphite oxide used as reinforcement in composites synthesized from cellulose acetate and polyacrylic acid

Abstract

This work focused on the synthesis and characterization of composites, obtained based on polyacrylic acid and cellulose acetate, which incorporated graphite oxide and graphene oxide as structural reinforcement. The composites were obtained using the phase inversion method and the incorporation of the reinforcement, during the synthesis process, was carried out in proportions of 1% by weight. The characterization of the composites was carried out using IR, Raman, BET, SEM spectroscopy techniques and methods for determining acidic and basic sites. The results obtained showed that it is possible to synthesize composites that present a network configuration, made up of layers that give the material the effect of depth. Furthermore, it was possible to observe that both graphite oxide and graphene oxide were deposited on the outer edge of the hexagonal pores present in the material. Finally, the concentration values of acidic and basic sites were obtained. The presence of these sites could be associated with carboxylic groups inserted during the oxidation of graphitic materials and with non-reactive sites present in cellulose.