Grain-growth kinetics of ferropericlase at high-pressure

Abstract

Grain-growth kinetics of (Mg 0.85Fe 0.15)O ferropericlase was investigated at pressures of 5 and 10 GPa and temperatures of 1673–1873 K using a Kawai-type multi-anvil apparatus. Presintered ferropericlase aggregate with an average grain size of 4.0 μm was used as starting material of grain-growth annealing experiments. The grain-growth kinetics of ferropericlase is described by G n − G 0 n = k 0 t exp [ − ( E * + P V * ) / R T ] , where G is the average grain size at annealing time t, G 0 the initial average grain size, P the pressure, R the gas constant and T is the absolute temperature, with n = 2.6 ± 0.4, log 10 k 0 = −7.5 ± 1.7 m 2.6/s, E * = 262 ± 30 kJ/mol, V * = 4.7 ± 0.7 cm 3/mol. Compared at same pressure and temperature, grain-growth rate of ferropericlase is similar to olivine and faster than those of wadsleyite and ringwoodite. The present results show that, at the top of the lower mantle ( P = 25 GPa and T = 1773 K) grain size of ferropericlase in single phase system evolves to ∼2 × 10 −2 m after significant geological time (10 My) while a previous study predicts that grain size of MgO in two-phase system is as small as ∼8 × 10 −6 m at same condition.