Abstract
Grain-boundary migration controls grain growth, which is important in material processing and synthesis. When a vertical grain boundary ends at a horizontal free surface, a groove forms at the tip to reduce the combined grain-boundary and surface energies. The groove affects the migration of the grain boundary, and its effect must be understood. This work studies grain-boundary grooving by capillarity-driven surface diffusion with asymmetric and strongly anisotropic surface energies. The surface energies are described by the delta-function facet model that holds for temperatures above the roughening temperature of the bicrystal. Since the asymmetric anisotropy does not introduce a length scale, the asymmetric groove still grows with time t as t1∕4. Thus, the nonlinear partial differential equation that governs grooving is reduced by a self-similar transformation to an ordinary differential equation, which is then solved numerically by shooting methods. We vary systematically the crystallographic orientations of the bicrystal and the normalized grain-boundary energy. We find that the self-similar groove profile is faceted and asymmetric for most bicrystals. However, a few asymmetric bicrystals can also yield smooth and symmetric grooves. Some bicrystals may even form ridges instead of grooves. We also find that the asymmetric surface energies tilt the grain-boundary tip sideways, which induces the grain boundary to migrate. We show that anisotropic groove profiles measured in SrTiO3 and Ni can be well fitted by our model.
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