Abstract

Abstract Many textbooks give an inadequate, and even inaccurate, presentation of the laws established by Graham on diffusion and related topics. These laws are fundamental to the understanding of the motion of gases in porous solids, and, stemming to a considerable extent from applied research on reactions of gases in porous catalysts, and on gas-cooled nuclear reactors, a better appreciation of the significance of the laws has been attained in recent years. A survey is given of Graham's actual findings, and their relation to other investigations, in the light of recent research.

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