Abstract

In gold(I) derivatives of several nitrogen-containing heterocycles it was found that: (1) the metal is two- coordinated even when the formula may suggest otherwise; (2) when tautomers are possible, one or more AuN bonds, or even AuC bonds, are more readily formed then AuO bonds; (3) the presence of a (ligand) AuN group increases the tendency towards H-bond formation on another nitrogen of the heterocycle.

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