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Abstract
Armed/disarmed effect of propargyl glycosides in the presence of AuBr 3 is studied. Observed that oxophilic AuBr 3 cleaves interglycosidic bond of an armed disaccharide resulting in the formation of a disaccharide and a 1,6-anhydro sugar. Trisaccharides were obtained after fine tuning the reactivity of the glycosyl donor with different protecting groups.
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