Abstract

Gold mineralization related to a sulphide-bearing quartz vein within Triassic phyllites has been identified in a former study of an abandoned Cu–Zn–Pb mine in southern Tuscany–northern Latium. The vein-hosted mineral assemblage includes pyrite, sphalerite, chalcopyrite, galena, arsenopyrite, and tetrahedrite; the gold content reaches up to 20 ppm. The mineralization was related to fluids characterised by moderate temperatures and moderate salinities (5–15% NaCl equivalent) and represents the highest grade of Au in the ore deposits of southern Tuscany. The difference in the estimated values of Te of primary, L+ V, pseudo-secondary L+ V, secondary L+ V fluids inclusions reflects different components present in the solutions. Based on these results one can conclude that euhedral quartz and pyrite deposition was related to fluids having variable salinity and chemical components. The origin of gold in Ponte San Pietro (PSP) deposit may be related to leaching of metapelites/phyllites derived from pelitic rocks containing some amount of sulphur-bearing organic matter; it is worthy noting that quartz–marcasite bearing lenses, interstratified in Triassic phyllites, contain significant amount of visible gold. The Co, Ni, Mn, as well as the δ 34S data, suggest a different origin for the phyllite-hosted marcasite, the PSP quartz-vein hosted pyrite, and for gold occurrences.

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