Abstract

An efficient cascade annulation protocol was established to access substituted 2-hydroxybenzocarbazoles from alkynylcyclohexadienones and substituted 2-aminophenols under gold catalysis. In this transformation a new C-C, two C-N bonds were formed sequentially and moderate to excellent yields of 2-hydroxybenzocarbazole derivatives were obtained selectively via Meyer-Schuster rearrangement in one-pot.

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