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Abstract
The complexes Ph2SeAuCl (green) and Ph2SeAuCl3 (brown) are prepared by direct reaction between the diphenylselenide ligand and the corresponding gold chloride. The crystal structures confirm the presence of monomeric, linear (AuI) or square planar (AuIII) coordinated complexes with bond lengths A u(I)-Se 2.378(1), Au(III)-Se 2.445(1) Å. Short non-bonded contacts Au(I) ··· Au(I) and Au(III) ··· Cl are observed.
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