Abstract
AbstractAmino group is one of the most ubiquitous functional groups, and therefore the direct introduction of amino groups into arenes has gained much attention. Methods for installing amino groups into organic molecules are highly sought after. Herein, a direct C−H imidation under gold(I) chloride catalysis has been developed with N‐fluorobenzenesulfonimide as the imine source. The choice of ligand plays an important role where 2,2′‐biquinoline was found to be most efficient. Various polycyclic aromatic hydrocarbons were directly imidated under the newly established protocol.
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