Abstract
The interaction of 1-(2-acetamido-3,4,6,-tri-O-acetyl-2-deoxy-β-D-glucopyranosyloxy)benzotriazole with primary and secondary aliphatic and cycloaliphatic alcohols or diisopropylidenegalactose in refluxing methylene chloride under the catalysis of Lewis acids resulted in alkyl-O-glucosaminides with the 1,2-trans-configuration of the glycoside bond. Other glucosaminides of substituted hydroxylamine were shown not to react under these conditions. The structures of the synthesized glucosaminides were confirmed by 1H NMR spectroscopy and comparison with the authentic compounds.
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