Abstract
The title compound [systematic name: (methoxycarbonylmethyl)ammonium chloride], crystallizes as a salt, C3H8NO2 +·Cl−, with the charged species interacting mutually via strong and highly directional N+—H⋯Cl− hydrogen bonds which lead to the formation of a supramolecular tape running parallel to the c axis. Tapes close pack in the solid state mediated by multipoint recognition synthons based on weak C—H⋯O interactions and van der Waals contacts between adjacent methyl groups.
Highlights
The title compound [systematic name:ammonium chloride], crystallizes as a salt, C3H8NO2+Cl, with the charged species interacting mutually via strong and highly directional N+—H Cl hydrogen bonds which lead to the formation of a supramolecular tape running parallel to the c axis
Tapes close pack in the solid state mediated by multipoint recognition synthons based on weak C—H O interactions and van der Waals contacts between adjacent methyl groups
We are grateful to Fundação para a Ciência e a Tecnologia (FCT, Portugal) for their general financial support and for specific funding toward the purchase of the single-crystal diffractometer
Summary
C. Tomé,b Verónica de Zea Bermudez,c José A. S. Cavaleirob and João Rochaa a Department of Chemistry, University of Aveiro, CICECO, 3810-193 Aveiro, Portugal, bDepartment of Chemistry, University of Aveiro, QOPNA, 3810-193. Portugal, and cDepartment of Chemistry, CQ-VR, University of Trás-osMontes e Alto Douro, 5001-801 Vila Real, Portugal. The title compound [systematic name: (methoxycarbonylmethyl)ammonium chloride], crystallizes as a salt, C3H8NO2+Cl, with the charged species interacting mutually via strong and highly directional N+—H Cl hydrogen bonds which lead to the formation of a supramolecular tape running parallel to the c axis. Tapes close pack in the solid state mediated by multipoint recognition synthons based on weak C—H O interactions and van der Waals contacts between adjacent methyl groups
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