Abstract

The nanoenvironment provided by the neighboring dendra characteristically influences the redox potentials and the photophysical properties of the tetraphenylporphyrin–zinc (Zn-TPP; denoted as P in Figure) chromophore within the dendrimers 1, which are based on C60 as a structure-determining core. Such functional dendrimers represent a new prototype of model systems for heme proteins (1).

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