Abstract

Abstract Global analyses of satellite spectral observations indicate the existence of negative brightness temperature differences between 11 and 6.7 µm (BT11 −BT6.7) when cold scenes are viewed. Differences are typically greater than −5 K for the Tropics and midlatitudes but can be smaller than −15 K over high-altitude polar regions during winter. In July, more than 60% of the observations over the Antarctic Plateau had BT11 − BT6.7 < −5 K. In January, over Greenland, the frequency of occurrence is approximately 20%. Three factors are investigated that may contribute to these observed negative brightness temperature differences: 1) calibration errors, 2) nonuniform scenes within the field of view, and 3) physical properties of the observed phenomena. Calibration errors and nonuniform scenes may generate values of BT11 − BT6.7 that are less than zero; however, these differences are on the order of −2 K and, therefore, cannot fully explain the observations. A doubling and adding radiative transfer model is ...

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