Abstract

Objective: This study investigated the relationships between PM2.5 and 5 criteria air pollutants (SO2, NO2, PM10, CO, and O3) in Heilongjiang, China, from 2015 to 2018 using global and geographically and temporally weighted regression models. Methods: Ordinary least squares regression (OLS), linear mixed models (LMM), geographically weighted regression (GWR), temporally weighted regression (TWR), and geographically and temporally weighted regression (GTWR) were applied to model the relationships between PM2.5 and 5 air pollutants. Results: The LMM and all GWR-based models (i.e., GWR, TWR, and GTWR) showed great advantages over OLS in terms of higher model R2 and more desirable model residuals, especially TWR and GTWR. The GWR, LMM, TWR, and GTWR improved the model explanation power by 3%, 5%, 12%, and 12%, respectively, from the R2 (0.85) of OLS. TWR yielded slightly better model performance than GTWR and reduced the root mean squared errors (RMSE) and mean absolute error (MAE) of the model residuals by 67% compared with OLS; while GWR only reduced RMSE and MAE by 15% against OLS. LMM performed slightly better than GWR by accounting for both temporal autocorrelation between observations over time and spatial heterogeneity across the 13 cities under study, which provided an alternative for modeling PM2.5. Conclusions: The traditional OLS and GWR are inadequate for describing the non-stationarity of PM2.5. The temporal dependence was more important and significant than spatial heterogeneity in our data. Our study provided evidence of spatial–temporal heterogeneity and possible solutions for modeling the relationships between PM2.5 and 5 criteria air pollutants for Heilongjiang province, China.

Highlights

  • Air pollutants can be emitted from anthropogenic and natural sources and may be either emitted directly or formed in the atmosphere [1]

  • The Ordinary least squares regression (OLS) model indicated that PM2.5 increased as the 4 air pollutants (SO2, NO2, PM10, and carbon monoxide (CO)) increased, while PM2.5 increased as O3 decreased

  • This was evident by the negative correlation between PM2.5 and O3 (Figure 2), which was consistent with a previous study [40]

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Summary

Introduction

Air pollutants can be emitted from anthropogenic and natural sources and may be either emitted directly (primary pollutants) or formed in the atmosphere (as secondary pollutants) [1] They may be transported or formed over long distances and have influences on human health, ecosystems, the built environment, and climate in large areas. It has been confirmed by extensive epidemiological studies that air pollution is closely associated with increased risks of mortality or morbidity for cardiovascular and respiratory diseases [2,3,4,5]. Public Health 2019, 16, 5107; doi:10.3390/ijerph16245107 www.mdpi.com/journal/ijerph

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