Abstract

Etude par RPE, des radicaux libres produits par irradiation γ a 77 K de cycloalcanols «cristallins vitreux» en fonction de la temperature: mouvements intramoleculaires dans le domaine 10 7 -10 9 Hz au voisinage de la temperature de transition vitreuse, Tg. Analyse de la recombinaison radicalaire autour de T g : elle est regie par diffusion «chimique» dans le cas du cyclooctanol. Mouvements de reorientation rapide

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