Abstract
Glass-ceramic electrolytes of the Li1.5Al0.5Ge1.5(PO4)3-xB2O3 series (0≤x≤0.15 wt%) were obtained by glass crystallization under the same conditions of heat treatment. The influence of B2O3 addition on the phase composition and unit cell parameters of lithium-aluminium-germanium-phosphate glass-ceramics was investigated by XRD. The obtained solid electrolytes have the NASICON-type structure with space group R-3c. Glass-ceramics is single-phase at 0≤x≤0.15. Transport properties of glass-ceramics electrolytes were investigated by impedance spectroscopy. The conductivity of Li1.5Al0.5Ge1.5(PO4)3 was found to be lower compared to the B2O3-added solid electrolytes. Namely, the composition with 0.05 wt% has the highest lithium-ion conductivity, which is 5.5·10−4 S/cm at 25 °C. Also the thermal compatibility of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte with Li4T5O12 anode material and the influence of Li3BO3 addition on their compatibility were investigated by DSC method.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
