Abstract
Relaxor ferroelectrics (RFEs) are being actively investigated for energy storage applications due to their large electric-field-induced polarization with slim hysteresis and fast energy charging-discharging capability. Here, w e report a novel nanograin engineering approach based upon high kinetic energy deposition for mechanically inducing the RFE behavior in a normal ferroelectric Pb(Zr0.52 Ti0.48 )O3 (PZT), which results in simultaneous enhancement in the dielectric breakdown strength (EDBS ) and polarization. Mechanically transformed relaxor thick films with 4μm thickness exhibited an exceptional EDBS of 540 MV/m and reduced hysteresis with large unsaturated polarization (103.6 μC/cm2 ), resulting in a record high energy storage density of 124.1 J/cm3 and a power density of 64.5 MW/cm3 . This fundamental advancement is correlated with the generalized nanostructure design that comprises of nanocrystalline phases embedded within the amorphous matrix. Microstructure-tailored ferroelectric behavior overcomes the limitations imposed by traditional compositional design methods and provides a feasible pathway for realization of high-performance energy storage materials. This article is protected by copyright. All rights reserved.
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