Abstract
A study was carried out on the behavior of monomeric germylenes derived from pyridine-containing diols in reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone. It was found that the germanium atom increases its oxidation state to 4+ in these reactions. The structure of the product of the reaction with 9,10 phenanthrenequinone was confirmed by X-ray structural analysis, which showed a transannular germanium-nitrogen interaction in this product. Authors: M. Huang, M. M. Kireenko, K. V. Zaitsev, Yu. F. Oprunenko, A. V. Churakov, S. S. Karlov, and G. S. Zaitseva. English translation in Chemistry of Heterocyclic Compounds , 2011, 47 (12), pp 1584-1589 http://link.springer.com/article/10.1007/s10593-012-0950-1
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