Germanium Template Assisted Integration of Gallium Arsenide Nanocrystals on Silicon: A Versatile Platform for Modern Optoelectronic Materials

Abstract

AbstractMetal organic vapor phase epitaxy is used to grow gallium arsenide (GaAs) nanocrystals (NCs) on germanium (Ge) templates on nanoscopic silicon (Si) threads prepared by reactive ion etching. Scanning transmission electron microscopy with energy dispersive X‐ray measurements shows an epitaxial growth of the GaAs on the Ge template that is supported by the Si thread, and that Ge doping is induced to the GaAs by the template. On Ge templates of about 60 nm diameter, as‐grown GaAs NCs show a very regular rhombic‐dodecahedral outer shape that can be explained by a preferential growth along the <110> plane. Photoluminescence measurements of the Ge/GaAs structures reveal radiative emission peaks on top of the GaAs band‐to‐band emission and at sub‐band gap energies. While high energy peaks are originating from Ge acceptor levels in GaAs, sub‐band gap peaks can be explained by radiation from Ge donor and acceptor bands that are amplified by photonic modes hosted in the rhombic‐dodecahedral GaAs NCs. This study shows that a template‐assisted crystal growth at the nanoscale opens up routes for a versatile integration of strongly emitting nanomaterials for a use in on‐chip solid state lighting and photonics.