Abstract
Abstract In this work the geometric structure parameters and radial density distribution of 1s2s 1 S excited state of the two-electron atomic system near the critical nuclear charge Z c were calculated in detail under tripled Hylleraas basis set. Contrary to the localized behavior observed in the ground and the doubly excited 2p 2 3 P e states, for this state our results identify that while the behavior of the inner electron increasingly resembles that of a hydrogen-like atomic system, the outer electron in the excited state exhibits diffused hydrogen-like character and becomes perpendicular to the inner electron as nuclear charge Z approaches Z c. This study provides insights into the electronic structure and stability of the two-electron system in the vicinity of the critical nuclear charge.
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