Abstract
Shrinkage corrections of the microwave structures of H3NBF3 isotopomers resolve an apparent discrepancy between experimental and theoretical values of the NB bond length; ab initio10B, 11B and 14N nuclear quadrupole coupling constants are in qualitative agreement with experiment, confirming the earlier microwave characterisation of this donor–acceptor adduct and providing a physical picture of dative bond formation.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society Chemical Communications
Paper Title
Journal
Date
