Geological and Isotopic Constraints on the Metallogenic Evolution of the Proterozoic Sediment-Hosted Pb-Zn (Ag) Deposits of Brazil

Abstract

Integrated studies of seven Proterozoic sediment-hosted, Pb-Zn-Ag sulfide deposits of Brazil, permit the estimation of the age of the hosting sequence and the mineralization, the nature of the sulfur and metal sources, the temperature range of sulfide formation and the environment of deposition. These deposits can be classified into three groups, according to their ages. (a) Archean to Paleoproterozoic: the Boquira deposit, in Bahia state, consists of stratiform massive and disseminated sulfides hosted by parametamorphic sequences of grunnerite-cummingtonite+magnetite that represent a silicate facies of the Boquira Formation (BF). Lead isotope data of galena samples indicate a time span between 2.7 and 2.5 Ga for ore formation, in agreement with the stratigraphic position of the BF. The relatively heavy sulfur isotope compositions for the disseminated and stratiform sulfides (+8.3 to +12.8 ‰ CDT)suggest a sedimentary source for the sulfur. (b) Paleo to Mesoproterozoic: stratiform and stratabound sulfides in association with growth faults are present in the Canoas mine (Ribeira, in Paraná state) and in the Caboclo mineralization (Bahia state). They are hosted by calcsilicates and amphibolites in the Canoas deposit, whereas in the Caboclo area the mineralization is associated with hydrothermally altered dolarenites at the base of the 1.2 Ga Caboclo Formation. The interpreted Pb-Pb age of the Canoas mineralization is coeval with the 1.7 Ga host rocks. Sulfur isotopic data for Canoas sulfides (+1.2 to +16 ‰ CDT) suggest a sea water source for the sulfur. The range between −21.1 and +8.8 ‰ CDT for the Caboclo sulfides could suggest the action of bacterial reduction of seawater sulfates, but this interpretation is not conclusive. (c) Neoproterozoic: stratiform and stratabound sulfide deposits formed during the complex diagenetic history of the host carbonate rocks from the Morro Agudo (Bambui Group), Irecê and Nova Redenção (Una Group), yield heavy sulfur isotope values (+18.9 to +39.4 ‰ CDT). The uniform heavy isotope composition of the barites from these deposits (+25.1 to +40.9 ‰) reflect their origin from Neoproterozoic seawater sulfates. The late-stage, and most important, metallic concentrations represent sulfur scavenged from pre-existing sulfides or from direct reduction of evaporitic sulfate minerals. Lead isotope data from the Bambui Group suggest focused fluid circulation from diverse Proterozoic sediment sources, that probably was responsible for metal transport to the site of sulfide precipitation. (d) Late Proterozoic to Early Paleozoic: lead-zinc sulfides (+pyrite and chalcopyrite) of Santa Maria deposits, in Rio Grande do Sul, form the matrix of arkosic sandstones and conglomerates, and are closely associated with regional faults forming graben structures. Intermediate volcanic rocks are intercalated with the basal siliciclastic members. Lead isotope age of the mineralization (0.59 Ga) is coeval with the host rocks. Sulfur isotopic values between −3.6 and +4.1 are compatible with a deep source for the sulfur. Geological, petrographic and isotopic data of the deposits studied suggest that they were formed during periods of extensional tectonics. Growth faults or reactivated basement structures probably were responsible for localized circulation of metal-bearing fluids within the sedimentary sequences. Sulfides were formed by the reduction of sedimentary sulfates in most cases. Linear structures are important controls for sulfide concentration in these Proterozoic basins.