Abstract

The paper presents the results of a comprehensive major element, trace element, and Sr-Nd-Pb-Hf isotopic study of Mid-Tertiary volcanic sequences from the northwestern flood basalt province in Ethiopia. The volcanic rocks studied range in composition from basanites, alkaline basalts, and ankaramites, which form the 1st three sequences at the base associated with basaltic agglomerate (sequence 1, 2 and 3) to transitional and tholeiitic basalts and picrites confined to the upper three sequences (sequences 4, 5 and 6). Sequence 5 is bimodal with intermediate-felsic pyroclastic rocks intercalating the transitional-tholeiitic basalts. There is a good correlation of sequences with geochemical enrichments, such as an increase La/LuN with TiO2, and decrease in Al2O3 and SiO2 towards the base. The smooth increase of La/LuN ratios in lower sequences reflect the general decrease of degree of partial melting that sampled heterogeneous packages of mantle plume materials. In the Sr-Nd isotopic diagram two clusters are formed one with restricted and low- Sr- (0.70356-0.70345) and Nd- (0.51290-0.51284) isotopic compositions, defined by sequence 1, and the other cluster with relatively higher 87Sr/86Sr (0.7052-0.7036) and 143Nd/144Nd (0.51296-0.5127) isotopic compositions defined by samples from sequence 2, and most other sequences with little scatter. The Pb-isotopic compositions vary systematically within each sequence (from base to top), and each sequence clustered systematically in a different Pb–Pb– isotopic space with the highest 206Pb/204Pb (19.10-19.30) and 207Pb/204Pb (15.60-15.65) measured in sequence 1, quite differently from other sequences and from previously reported for northwestern Ethiopian flood basalt province, and the lowest 206Pb/204Pb (18.20-18.56) and 207Pb/204Pb (15.51-15.55) measured in sequence 4. Sequence 2 and 3 lavas display a similar 206Pb/204Pb and 207Pb/204Pb ranges falling between sequence 1 and 4. In contrast, sequence 6 samples displayed towards higher 206Pb/204Pb than sequence 2, 3, and 4, but with lower and higher 207Pb/204Pb than sequence 1 and 5 respectively. The lavas of sequence 1 and 4 have relatively less radiogenic 176Hf/177Hf than other sequences with slight scatter. The systematic geochemical variations in lavas are remarkable and reflects three mantle end component mixing with minimal crustal in put as a fourth component. The enriched sequence 1 has very similar geochemistry to HIMU-type ocean island basalts (OIBs), and this end member ascribed to be the most enriched Afar plume component 1, which is the most enriched Afar Plume component during initial continental break. The second enriched component is defined by sequence 2 and 3 samples and may reflect the second enriched component in Ethiopian flood basalt, previously reported for the high-Ti2 basalts assumed to be the enriched Afar Plume component, whereas the third component is the depleted component defined by sequence 4 partly overlap the range previously reported for low-Ti basalts. Keywords: Flood basalts, Geochemistry, Sr-Nd, Pb-Pb, Hf-Hf isotopes, Afar Plume, Partial melting, Crustal input

Highlights

  • The Mid-Tertiary (~30 Ma) Ethiopian continental flood basalts form part of the larger Afro-Arabian Igneous Province, which is related to the Afar plume and the Red Sea-Gulf of Aden

  • Pik et al (1998, 1999) have classified the north-western Ethiopian flood basalts into three distinct geochemical groups based on trace element and Ti concentrations: low-Ti basalts (LT), high-Ti1 (HT1) basalts and high-Ti2 (HT2) basalts

  • This paper presents geology map of part Maychew area dominated by high-Ti basalts (Figs.1; 2 & 3)

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Summary

INTRODUCTION

The Mid-Tertiary (~30 Ma) Ethiopian continental flood basalts form part of the larger Afro-. The area, of present study (Fig. 1) forms part of the high-Ti basalts of Ethiopian flood basalt province. At present there is no geochronological data available for Maychew lavas to verify the sequential variations, but the earlier K-Ar whole-rock age dating of basalts collected from 110 m and 140 m above base in Maychew area gave 26.2 Ma and 25.7 Ma (Jones, 1976), respectively Such a young age compared to the current refined and accepted mineral 40Ar/39Ar age of 30.9 and 29.2 Ma for the northwestern Ethiopian continental flood lavas (Hofmann et al, 1997; Coulie et al, 2003; Kieffer et al, 2004) could be related to the unrecognized argon loss or gain in these intensely weathered formations. There is systematic variation in the characteristics of the dominant volcanic rocks from the base (1800 m, Mehoni plain) of the Maychew volcanic sequence to the summit at the Tsibet Mountain (3780 m) (Figs. 2 & 3) and these sequences are described below

Sequence 1
Sequence 2
Sequence 3
Sequence 4
Sequence 5
Sequence 6
SAMPLING STRATEGY AND ANALYTICAL METHODS
RESULTS AND DISCUSSION
Isotope variations
CONCLUSION
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