Geographical origin discrimination of Anisodus tanguticus (Maxim.): Chemometrics methods applied to ICP-OES analysis

Abstract

Anisodus tanguticus (Maxim.) Pascher, which is an important species used in traditional Tibetan medicine, is grown on the Qinghai–Tibet Plateau. A quantitative analysis of 18 elements in A. tanguticus and the soil was conducted using an inductively coupled plasma optical emission spectrometer. The elemental contents of A. tanguticus underwent principal component analysis, linear discriminant analysis, and orthogonal partial least-squares discriminant analysis. Furthermore, elemental accumulation and elemental transfer coefficients were calculated, and the correlation between environmental factors and elemental content was further explored. The multivariate statistical results indicated that A. tanguticus plants can be distinguished by their geographical origin. Elemental accumulation and transfer patterns differed significantly among the analysed elements. Some positive or negative correlation relationships were found between environmental factors and contents in root parts of A. tanguticus. The present study provides an efficient and practical method to discriminate the geographical origin of A. tanguticus from different regions.