Abstract
High-uranium (U) coal is the dominant form of coal in Southwestern China. However, directly utilizing this resource can also harm the environment because this element is radioactive; it is, therefore, necessary to clean this kind of coal before burning. This research studied the geochemistry of toxic elements and their partitioning during the preparation of high-U coal in China. The results show that high-U coals are mainly distributed in Southwestern China and are characterized by a high organic sulfur (S) content and vanadium (V)-chromium (Cr)-molybdenum (Mo)-U element assemblage. These elements are well-correlated with one another, but are all negatively related to ash yield, indicating that all four are syngenetic in origin and associated with organic materials. A mineralogical analysis shows that U in Ganhe and Rongyang coal occurs within fine-grained anatase, clay minerals, guadarramite, and pyrite, while V occurs in clay minerals, pyrite, and dolomite, and Cr occurs in dolomite. Other elements, such as fluorine (F), lead (Pb), selenium (Se), and mercury (Hg), mainly occur in pyrite. By applying a gravity separation method to separate minerals from coal, the content of the enrichment element assemblage of V-Cr-Mo-U in Rongyang coal is still shown to be higher than, or close to, that of the original feed because this element assemblage is derived from hydrothermal fluids during syngenetic or early diagenetic phases, but other elements (beryllium [Be], F, manganese [Mn], zinc [Zn], Pb, arsenic [As], Se, Hg) can be efficiently removed. Once cleaned, the coal obtained by gravity separation was subject to a flotation test to separate minerals; these results indicate that while a portion of V and Cr can be removed, Mo and U remain difficult to extract. It is evident that the two most commonly utilized industrialized coal preparation methods, gravity separation and flotation, cannot effectively remove U from coal where this element occurs in large proportions. Finally, dilute hydrochloric acid (HCl) leaching experiments show that the majority of Mo and a portion of V, Cr, and U are adsorbed in clay minerals and organic matter and, therefore, exist in an adsorbed state. In this state, these elements can be removed using the acid method. Thus, as U cannot be fully removed from coal, the use of high-U coals is not recommended.
Highlights
Coal resources in China are unevenly distributed; the reserves in the southwest of the country comprise ~10% of the total [1]
Previous reports showed that some coals in Southern and Southwestern China are rich in U, including those from Yanshan in Yunnan Province [2], as well as Heshan [3], Fusui [4], and Yishan [5] from Guangxi Province, Chenxi from Hunan Province [6], and Guiding from Guizhou Province [7]; these coals are referred to as “high-U coals” [7]
Lauer et al [15] showed that coal ash residues derived from coals with U occurring at concentrations greater than 10 ppm exceed the standards for radiation in building materials, while Melo and Burkart [16] showed that U-rich ultra-fine particles released from coal during combustion from coal-fired power plants are harmful to human health
Summary
Coal resources in China are unevenly distributed; the reserves in the southwest of the country comprise ~10% of the total [1]. The current, most commonly applied approach to do this is gravity separation, which uses differences in density to separate minerals from coal [27]; in contrast, limited research has been carried out on the removal of toxic elements from coal by flotation using differences in surface properties to separate minerals from coal [28,29]. Our previous work in this area has shown that the elements U, V, Cr, and Mo in high-U coal occur in organic matter and in fine-grained minerals; these elements, cannot be removed from coal by gravity separation [31]. Toxic elements from the Ganhe cleaned coal obtained by flotation were extracted using dilute HCl, while the geochemistry of U and other toxic elements from Rongyang and Ganhe were analyzed in this study to provide a sound theoretical basis for the removal of toxic elements from high-U coal
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
