Geochemistry of tin (Sn) in Chinese coals.

Abstract

Based on 1625 data collected from the published literature, the geochemistry of tin (Sn) in Chinese coals, including the abundance, distribution, modes of occurrence, genetic types and combustion behavior, was discussed to make a better understanding. Our statistic showed the average Sn of Chinese coal was 3.38mg/kg, almost two times higher than the world. Among all the samples collected, Guangxi coals occupied an extremely high Sn enrichment (10.46mg/kg), making sharp contrast to Xinjiang coals (0.49mg/kg). Two modes of occurrence of Sn in Chinese coals were found, including sulfide-bounded Sn and clay-bounded Sn. In some coalfields, such as Liupanshui, Huayingshan and Haerwusu, a response between REEs distribution and Sn content was found which may caused by the transportation of Sn including clay minerals between coal seams. According to the responses reflecting on REEs patterns of each coalfield, several genetic types of Sn in coalfields were discussed. The enrichment of Sn in Guangxi coals probably caused by Sn-rich source rocks and multiple-stage hydrothermal fluids. The enriched Sn in western Guizhou coals was probably caused by volcanic ashes and sulfide-fixing mechanism. The depletion of Sn in Shengli coalfield, Inner Mongolia, may attribute to hardly terrigenous input and fluids erosion. As a relative easily volatilized element, the Sn-containing combustion by-products tended to be absorbed on the fine particles of fly ash. In 2012, the emission flux of Sn by Chinese coal combustion was estimated to be 0.90×10(9)g.