Geochemistry of Precambrian and Paleozoic siliciclastic rocks from the Iberian Range (NE Spain): implications for source-area weathering, sorting, provenance, and tectonic setting.

Abstract

The major and trace element chemical composition of Precambrian and Paleozoic shales and sandstones from the Iberian Range (Spain) has been investigated to determine the provenance and tectonic setting of these rocks, as well as to appraise the influence of the weathering, hydraulic sorting and recycling processes upon source rock signature. The samples studied belong to a prograde sequence from diagenesis to anchizonal grade, and are mainly composed of quartz, illite/mica phases and/or kaolinite, with chlorite, feldspars, and carbonates as minor components. The major element distribution (Chemical Index of Alteration (CIA) indices) reflects that recycling processes have been important in homogenizing the composition of shales and sandstones. The higher CIA indices observed in the Silurian and Devonian shales (80 and 85, respectively) compared with those of Precambrian to Ordovician and the Carboniferous age (about 70) indicate that their source area underwent more intense chemical weathering processes, possibly due to climatic and/or tectonic variations. Alternatively, the source area of the Silurian and Devonian shales may have been composed of recycled sedimentary materials. Mineral fractionation is mainly observed in coarser rocks through zircon, apatite and xenotime accumulation, although the shales are not free of these phases. The zircon content of the fine-grained rocks is not high enough to affect rare earth element (REE) contents, but phosphate minerals (apatite and xenotime) at least partially control the REE distribution. The influence of apatite and xenotime are slightly higher in the Precambrian shales as the phosphate concentration produces a decrease in the La/Sm ratios. Chondrite-normalized REE patterns and negative Eu anomaly size of the studied rocks are similar to that of Post-Archean Australian shales (PAAS) indicating that they originally come from a differentiated silicic source. The higher REE contents in the studied shales in relation to PAAS indicate that recycling processes in the Iberian Range sources were probably more intense than that of PAAS. The slight differences among the REE patterns of the different groups of shales probably do not reflect changes in source-area composition, but instead suggest variations in mineral sorting, chemical weathering and/or sediment recycling. The Th/Sc, Co/Th, Cr/Th, Cr/V, V/Ni ratios support a primitive silicic source for these rocks, with the higher Th/Sc and lower Co/Th in Cambrian and Ordovician shales indicating a higher proportion of felsic material in their primitive source area. The compositional maturity of analyzed sandstones is typical of cratonic environments and their La, Sc, Th and Zr contents reflect their passive continental margin setting.