Geochemistry of Middle Permian lacustrine shales in the Jimusar Sag, Junggar Basin, NW China: Implications for hydrothermal activity and organic matter enrichment

Abstract

Organic matter enrichment in black shales has frequently been linked with hydrothermal activity. However, it is poorly understood how hydrothermal activity affected paleo-environments and the enrichment of organic matter in ancient lacustrine sediments. The hydrothermal activity recorded in the Middle Permian Lucaogou Formation (LCGF) in the Jimusar Sag, Junggar Basin, Northwest China, provides an ideal sedimentary archive to explore this issue. The mineralogical composition, major and trace element, total organic carbon, and sulfur content of forty-three shale samples of the LCGF were investigated to better understand how hydrothermal activity influences organic matter enrichment in lacustrine shales. The terrigenous influx, redox conditions, paleoproductivity, hydrothermal effects, and organic matter enrichment mechanisms are discussed. The results show that the terrigenous influx is insufficient overall, and the lower section of the LCGF has less detrital materials than the upper section. The redox conditions of the bottom water of the lake in the Jimusar Sag during deposition of the LCGF were suboxic to anoxic, which, combined with relatively high paleoproductivity, is favorable for organic matter enrichment. Hydrothermal activity occurred more frequently during deposition of the lower section compared with the upper section of LCGF. Hydrothermal fluids provided sufficient nutrients to enhance organic matter production during deposition of the LCGF and resulted in organic matter enrichment.