Geochemistry of an ultramafic-rodingite rock association in the Paleoproterozoic Dixcove greenstone belt, southwestern Ghana

Abstract

Rodingite occurs in ultramafic rocks within the Paleoproterozoic (Birimian) Dixcove greenstone belt in southwestern Ghana. U–Pb analyses of zircons from granitoids intrusive into the greenstone belt constrain the age of the rodingite-ultramafic association to be older than 2159 Ma. The ultramafic complex consists of variably serpentinized dunite and harzburgite overlain by gabbroic rocks, which together show petrographic and geochemical characteristics consistent with their formation by fractional crystallization involving olivine and plagioclase cumulates. Major and trace element concentrations and patterns in the ultramafic–mafic cumulate rocks and associated plagiogranite are similar to rocks in ophiolitic suites. The rodingites, which occur as irregular pods and lenses, and as veins and blocks in the serpentinized zones, are characterized by high Al 2O 3 and CaO contents, which together with petrographic evidence indicate their formation from plagioclase-rich protoliths. The peridotites are highly depleted in REE and display flat, chondrite-normalized REE patterns with variable, but mostly small, positive Eu anomalies whereas the rodingites, which are also highly depleted, with overall REE contents from 0.04 to 1.2 times chondrite values, display distinct large positive Eu anomalies. It is proposed that the rodingite-bearing Birimian ultramafic complex and associated pillowed greenstone belt basalts may represent fragments of a Paleoproterozoic oceanic lithosphere.