Geochemistry and Petrology of Reservoir and Cap Rocks in Zar-3 Pilot CO2 Storage Complex, SE Czechia

Abstract

The planned pilot CO2 storage Zar-3 is an oil field with a gas cap in the final production stage in the SE Czech Republic. It is composed of a dolomite Jurassic reservoir sealed by three different formations that differ significantly in lithology. Previous studies left open questions on the nature of pore space and connectivity and the quality of the seal in the future CO2 storage complex. Microscopic petrography of the reservoir suggests dolomitisation in shallow water followed by karstification and brecciation with fracture-correct-dominated porosity. The seal horizons have porosity limited to the micro- and nanoscales. The oil consists of significantly biodegraded black oil of Jurassic origin mixed with less biodegraded gasoline-range hydrocarbons. Biomarkers in the caprock bitumens trapped in nanopores show a genetic relationship to the reservoir oil. Gas in the not yet fully depleted gas cap of the field is of thermogenic origin with no contribution of microbial methane. The formation water has total dissolved solids typical of isolated brines not diluted by infiltrated fresh water. The geochemical characteristics of the storage system together with the fact that the initial oil column is about 105 m tall with another 150 m of gas cap suggest that the seals are efficient and the Zar-3 future storage complex is tight and safe.