Abstract

Geochemical concentrations were extracted for a short sediment core from Ebinur Lake, located in arid northwest China, and mathematical methods were used to demonstrate the complex pattern of the geochemical anomalies resulting from the temporal changes in natural and anthropogenic forces on the lake sediments. The first element assemblage (C1) (aluminum, potassium, iron, magnesium, beryllium, etc.) was predominantly terrigenous; among the assemblage, total phosphorus and titanium were generally consistent with aluminum except with regards to their surface sequences, which inferred the differences of source regions for terrigenous detrital material led to this change around ca. 2000AD. The second assemblage (C2) (calcium and strontium) was found to have a negative relationship with aluminum through a cluster analysis. The third assemblage (C3) included sodium and magnesium, which were influenced by the underwater lake environment and deposited in the Ebinur depression. The concentration ratio of C1/(C1+C2) was used as an indicator for denudation amount of detrital materials, which was supported by the values of magnetic susceptibility. The enrichment factors for heavy metals suggested that the influence of human activities on heavy-metal enrichment in Ebinur Lake region was not severe over the past century. Prior to the 1960s, geochemical indicators suggested a stable lacustrine environment with higher water levels. Beginning in the 1960s, high agricultural water demand resulted in rapid declines in lake water level, with subsequent increases of lake water salinity, as evidenced by enhanced sodium concentration in lake core sediments. During this period, anthropogenic activity also enhanced the intensity of weathering and the denudation of the Ebinur watershed.

Highlights

  • Geochemical elements in lake sediments can be influenced by both natural and anthropogenic processes, and these element assemblages can be used to investigate the contributions of PLOS ONE | DOI:10.1371/journal.pone.0155819 May 13, 2016Geochemical Responses to Anthropogenic Influences in Northwest China different forcing mechanisms to changes in sedimentary environments [1, 2]

  • The results show that: (1) most elements, including Al, potassium (K), beryllium (Be), barium (Ba), titanium (Ti), sodium (Na), magnesium (Mg), zinc (Zn), vanadium (V), lead (Pb), cobalt (Co), chromium (Cr), nickel (Ni) and iron (Fe), had a similar distribution pattern which generally increased with depth

  • (2) Na and Mg had a negative correlation with Al. (3) In general, calcium (Ca) and strontium (Sr) increased with depth, similar to Al; the wave direction of Ca and Sr was opposite to that of Al. (4) The trends of total phosphorus (P) and Ti were similar to Al; at the sediment surface the trend of these elements was inconsistent with that of Al

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Summary

Introduction

Geochemical Responses to Anthropogenic Influences in Northwest China different forcing mechanisms to changes in sedimentary environments [1, 2]. Based on studies examining long-term paleo-environmental changes in lacustrine environments, natural processes affect the transportation of geochemical elements from watersheds to lakes [3,4,5]. Lacustrine sediments provide historic records of natural evolution and anthropogenic influences on lakes and their watersheds [9,10,11,12]. It is important to understand how climatic variations and anthropogenic activities influence the concentrations of geochemical constituents, especially heavy metals. Sediment cores can provide chronologies of metal concentrations in sedimentary sequences, and have been used to reveal human influences on heavy metal accumulation. The history of contamination in the arid environments of socially developing regions, northwest China, has not been widely studied in comparison to developed regions

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