Geochemical characteristics and genetic origin of crude oil in the Fushan sag, Beibuwan Basin, South China Sea

Abstract

Abstract The Fushan sag is an important petroleum-bearing unit in the Beibuwan Basin, South China Sea. However, genetic relationship between oil and source rocks has not been well understood. In this work, 43 mudstone samples and 22 crude oil samples in the sag were collected for molecular geochemical and isotopic analyses to investigate this relationship. The geochemical data shows that the mudstones in Liushagang formation have poor to good oil generation potential with TOC ranging from 0.45 to 2.19 wt% and the kerogen is mainly type Ⅱ. Two types of crude oils were identified in this study. The first type of Group A oils including the subgroup A1 and subgroup A2 has the characteristics of low maturity with low saturated hydrocarbon content and lighter δ13C values in the Huachang uplift. The source rocks for the Group A oils were deposited under suboxic to oxic and freshwater environment containing more terrestrial higher plant and less angiosperm. The subgroup A1 oils in Els11 reservoirs are separated from subgroup A2 in the Els12 reservoirs by relatively lower maturity. The subgroup A1 and subgroup A2 oils are closely related to the Els1 to Els21 and Els12 to Els21 source rocks, respectively. While the second type of oils including Group B and Group C oils has higher level of maturity with higher saturated hydrocarbon content and heavier δ13C values. The source rocks of Group B oils were deposited in a freshwater environment with lower salinity, and more angiosperms and terrestrial higher plants input than those of Group C oils. Two subgroups are divided in the Group B oils, of which subgroup B1 oils have higher maturity and their source rocks were deposited in lower salinity with more terrestrial higher plant input than that of subgroup B2 oils. The subgroup B1 oils occurring in the Els31 reservoirs from the Huachang uplift are likely related to Els31 source rocks, while subgroup B2 oils in the Els22 reservoirs from the southern slope area of the Bailian subsag is linked with mixed source of Els22 and Els31 mudstones. The Group C oils are distributed in Els22 and Els31 reservoirs in the Huachang uplift and their oil source are from Els32 mudstones. Two petroleum plays are likely divided by the mfs in Els2 based on the oil-source correlation in the sag. Group B and Group C oils belong to the lower play, and Group A oils only occur in the upper play. The distribution and accumulation of different groups of oils are mainly controlled by the special two-layered tectonostratigraphic framework and the transport ability of fault zone in the sag. This study clarifies the types of oils, as well as the oil-source correlation and the spatial distribution of different groups of oils. The results could benefit the further petroleum exploration and resource evaluation in the sag.