Geochemical and mineralogical evidence for the supergene origin of kaolin deposits – Central Main Ethiopian Rift

Abstract

The Belessa kaolin deposit in the western margin of the Central Main Ethiopian Rift was studied using geological, mineralogical, chemical and physical methods to understand its genesis and evaluate its potential suitability for different industrial applications. X-ray diffraction and Scanning Electron Microscopy were used to establish the mineralogical composition. Bulk chemical compositions were determined using ICP-MS and ICP-AES. The geology of the kaolin district is comprised of Miocene to Quaternary age rhyolite and pyroclastic tuff. The kaolin occurrence is located in the central part of the study area and is associated with rhyolite. The host rock is composed of quartz and alkali feldspar phenocrsyts set in a groundmass of very fine grained quartz, alkali-feldspar and plagioclase. The rhyolite is partially to completely altered to kaolin. The kaolin deposit is composed predominantly of kaolinite and quartz. The kaolinite minerals of the deposit have high structural order. The geological, mineralogical and geochemical studies indicate that supergene alteration played a major role in the formation of the Belessa kaolin deposit. The absence of quartz veining and alteration zones containing high temperature minerals precludes significant hypogene alteration. The Chemical Index of Alteration (CIA) and Chemical Index of Weathering (CIW) also show that the host rock experienced strong alteration and weathering. Furthermore, high Ce+Y+La values correspond to supergene-type alteration. The low P and high Cr+Nb concentrations also support a supergene origin. The physical properties, chemistry, mineralogy and crystal morphology indicate that the Belessa kaolin has potential applications for paper coating, filler (in paper, rubber, plastic and paint), ceramics, pharmaceuticals and cosmetics.