Abstract

A field, petrographic and geochemical study of two Triassic–Jurassic carbonate successions from the Maritime Alps, SE France, indicates that dolomitization is related to episodic fracturing and the flow of hydrothermal fluids. The mechanism governing hydrothermal fluids has been documented with the best possible spatio-temporal resolutions specifying the migration and trapping of hydrothermal fluids as a function of depth. This is rarely reported in the literature, as it requires a very wide range of disciplines from facies analysis (petrography) to very diverse and advanced chemical methods (elemental analysis, isotope geochemistry, microthermometry). In most cases, our different recognized diagenetic phases were mechanically separated on a centimetric scale and analyzed separately. The wide range of the δ18OVPDB and 87Sr/86Sr values of diagenetic carbonates reflect three main diagenetic realms, including: (1) the formation of replacive dolomites (Type I) in the eogenetic realm, (2) formation of coarse to very coarse crystalline saddle dolomites (Types II and Type III) in the shallow to deep burial mesogenetic realm, respectively, and (3) telogenetic formation of a late calcite cement (C1) in the telogenetic realm due to the uplift incursion of meteoric waters. The Triassic dolomites show a lower 87Sr/86Sr ratio (mean = 0.709125) compared to the Jurassic dolomites (mean = 0.710065). The Jurassic calcite (C1J) shows lower Sr isotopic ratios than the Triassic C1T calcite. These are probably linked to the pulses of the seafloor’s hydrothermal activity and to an increase in the continental riverine input during Late Cretaceous and Early Cenozoic times. This study adds a new insight into the burial diagenetic conditions during multiple hydrothermal flow events.

Highlights

  • The formation of low- versus high-temperature dolomites in carbonate successions is attributed to separate diagenetic conditions and fluid origins [1,2]

  • The main conclusions derived from this integrated field, petrographic and geochemical study of dolomitization in the Mesozoic carbonate succession, Provençal Domain, Maritime Alps, SE France show that: 1

  • The succession is extensively dolomitized with abundant breccia and zebra textures, and complex fracturing paths due to the influence of repeatedly injections of hydrothermal fluids

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Summary

Introduction

The formation of low- versus high-temperature dolomites in carbonate successions is attributed to separate diagenetic conditions and fluid origins [1,2]. Low temperature dolomitizing fluids are associated with near surface diagenetic fluids [3,4,5]. Hot dolomitizing fluids are either the result of Minerals 2020, 10, 775; doi:10.3390/min10090775 www.mdpi.com/journal/minerals. Minerals 2020, 10, 775 high burial temperatures or the flux of hot hydrothermal (HT) fluids into colder, shallower buried carbonate succession environments [6,7,8,9]. The HT fluids are commonly formed by the upward flow of basinal brines [10], or deeply percolating meteoric waters [11] that interact with crystalline basement rocks [12].

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