Abstract

Laser-induced breakdown spectroscopy (LIBS) is an ideal method for elemental analysis of geological samples. Although X-ray fluorescence (XRF) can measure a wide variety of elements, it struggles to measure elements lighter than silicon, meaning that many key crustal elements cannot be measured. In addition, as a fast, standoff method, LIBS can be employed in a variety of geometries with various distances from the target. LIBS has famously been employed by the National Aeronautics and Space Administration (NASA) on their Mars rovers, first in the ChemCam instrument and now in the SuperCam instrument. This article summarizes both the basic methodology and the most successful calibration and quantification methods to date.

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