Geo-spatial distribution of arsenic contamination of groundwater resources in intricate crystalline aquifer system of Central India: Arsenic toxicity manifestation and health risk assessment

Abstract

The behavior of As in aqueous media in the complex crystalline aquifers like that of the present study area is not yet understood properly. To that end, groundwater and river water samples from two different seasons are analyzed for As and physicochemical parameters. The groundwater in the area is evolved by simple dissolution or mixing of two or more different facies (Ca2+–Mg2+–Na+–SO4 2–). However, the majority of samples with the base-exchange indices (85%) and meteoric genesis indices (77%) value less than unitary (<1) divulges that Na+– SO4 2– type water and deeper meteoric percolation. The estimation of As in groundwater (<0.1–202 ppb) shows the spatial and temporal inconsistency with 17.31% (pre-monsoon) and 11.67% (post-monsoon) of the samples surpassed the permissible limit of 10 ppb. Furthermore, health risk associated with As in terms of hazard quotient (HQ) values > 1 (pre-monsoon: 21.15% and post-monsoon: 20%) for children and carcinogenic risk values >1.00 × 10−6 for different seasons (44.25% and 33.33% of samples) represents a serious health risk. Furthermore, the different stages of Keratosis and Melanosis diseases reported in the study area establish the severity of As toxicity on the local populace. The study concludes geogenic arsenic contamination in the study area is primarily associated with Rhyolite and its comagmatically formed Dongargarh granite batholith emplacements.