Abstract

Proton Exchange Membrane (PEM) water electrolysis system is one of the promising technologies to produce green hydrogen from renewable energy sources (wind and solar). However, performance and dynamic analysis of PEM water electrolysis systems are challenging due to the intermittent nature of such sources and involved multi-physical behaviour of the components and subsystems. This study proposes a generic dynamical model of the PEM electrolysis system represented in a modular fashion using Bond Graph (BG) as a unified modelling approach. Causal and functional properties of the BG facilitate the formal PEM electrolyser model to adapt and to fit the different configurations of the electrolyser ranging from laboratory scale to industrial scale. The system-specific key parameter values are identified optimally for a laboratory-scale electrolyser system running on a multi-source energy platform using experimental data. The mean absolute percentage error between simulation and experimental data is found to be less than 5%. The performance characteristic curves of the electrolyser are predicted at different operating temperatures using the identified key parameters. The predicted performance is in good agreement with the expected behaviour of the electrolyser found in the literature. The model also estimates the different energy losses and the real-time efficiency of the system under dynamic inputs. With these capabilities, the developed model provides an economical mean for design, control, and diagnosis development of such systems.

Highlights

  • Using hydrogen as storage for surplus electricity from Renewable Energy Sources (RES) has gained popularity in recent years due to its numerous advantages

  • Bond Graph (BG) can be denoted as G(N, B), where nodes N represent the BG elements that correspond to energetic physical elements, source elements, power/energy constraint BG connecting elements and technological elements and bonds B represent the set of oriented edges that correspond to power/energy exchange among nodal elements

  • The platform consists of two photo-voltaic panels (200 W power per panel), permanent magnet type wind turbine (350–400 W power) and two batteries running a commercial 300 W single cell Proton Exchange Membrane (PEM) electrolyser

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Summary

Introduction

Using hydrogen as storage for surplus electricity from Renewable Energy Sources (RES) has gained popularity in recent years due to its numerous advantages. Recent work in Reference [20], equivalent electrical circuit model for a PEM electrolyser has been proposed for studying the influence of different operating conditions and power electronics ripples effect on the cell voltage. In Reference [24], a graphical approach based on Bond Graph (BG) has been proposed for global modelling of PEM electrolyser system with its auxiliaries It incorporates the interaction of different phenomena such as fluidic, mass transport, electro-chemical and thermal for behavioural and performance analysis of the electrolyser. The modelling of complex multi-physics systems like PEM electrolyser is one of the most crucial tasks for studying the real behaviour of components, subsystems and overall system behaviour under dynamic intermittent operations.

BG Technique for Model Building
BG Elements and BG Variables
Different Levels of Modelling Abstraction
Grammar and Connectivity Rules
PEM Electrolyser Modelling
Technological Representation
Stack Model
Converter Sub-Model
Separator Sub-Models
H O n out
Cooling and Recirculation Circuits
Hydrogen Purification Subsystem
System Enclosure
Efficiency of the PEM Electrolysis System
Efficiency of System Including the Auxiliaries
Experimental Validation and Results
Conclusions
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