Generation of Ultrafine Particles by Spark Discharging

Abstract

Ultrafine carbon, metal, and metal oxide particles were generated with a commercially available spark generator designed for the production of carbon particles. Aerosols with number concentrations up to 107 cm−3 were produced at flow rates up to 150 lpm. Lognormal size distributions with modal diameters in the range of 18–150 nm and geometric standard deviations of about 1.5 were obtained. The chemical composition, size, number concentration, morphology, and surface area of the particles were varied, and the generation of particles with fixed characteristics could be maintained over many hours. The particle characteristics, however, could not be varied independently. For a certain chemical composition only size and number concentration were variable; morphology and surface area were fixed regardless of particle size. The particles grow by coagulation of primary particles formed by nucleation. The coagulated particles can either stick together and maintain their identity or fuse together and lose their ide...