Abstract
A phenylacetylene bearing an n-butylsulfoxide group, i.e., p-(n-butylsulfoxide)phenylacetylene (1) was prepared in high yields using the [Rh(norbornadiene)Cl]2–NEt3 catalyst in the presence of various solvents under mild conditions. The resulting polymer, poly[p-(n-butylsulfoxide)phenylacetylene] (poly(1)), was characterized in detail by 1H NMR, ESR, laser Raman, and diffuse reflective UV–vis methods. The data clearly showed that cis-to-trans isomerization of the polymer can be induced when pressure is imposed to the polymer at room temperature, rotationally breaking the cis CC bonds to generate the cis and trans radicals. Further, the spin density in the cis radical was migrated from the main-chain to the sulfoxide moiety as the side chain of the phenyl ring to magnetically interact with the first two methylene protons in the n-butyl group giving a triplet line ESR spectrum with an extremely large g value, g=2.0081.
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