Abstract
An extraordinary downfield-shifted 29 Si{1 H} NMR signal is seen at δ=338.5 for the platinum silylene complex [(dippe)(H)Pt=SiMes2 ][MeB(C6 F5 )3 ] (2). This remarkably stable metal silylene complex was obtained from 1 in the first intramolecular 1,2-hydride migration from silicon to a transition metal. dippe=iPr2 PCH2 CH2 PiPr2 , Mes=2,4,6-Me3 C6 H2 .
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