Abstract
Calming the radicals: Aminyl radicals may one day be useful oxidation catalysts if their thermodynamic instability can be overcome, for example, through complexation with a metal. The semiquinone–anilino-radical and catechol–anilino-radical complexes 1 and 2 have now been prepared and the anilino-radical character of the tetradentate amine ligand proved by electron paramagentic resonance and resonance Raman spectroscopy, as well as DFT calculations.
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